Sediment Contaminant Guideline exceeded or likely to be exceeded?
The general approach to use of the decision tree shown below is outlined in WQG - Section 3.1.5.
If
the lower sediment quality guideline, the trigger value, for a particular contaminant
is not exceeded, it is unlikely that it will result in any biological disturbance for
organisms inhabiting that sediment. If the trigger value is exceeded, either
management (including remedial) action is taken, or additional site-specific studies
are conducted to determine whether this exceedance poses a risk to the ecosystem.
Should a ‘low risk’ outcome result after continuous monitoring, there is scope to
refine the guideline trigger value.
It is important to compatre test sites with suitable references sites that provide background concentrations.
Exceedance of a trigger value is acceptable if it is at or below the
normal background concentration for a site.
Also any factors which might lower the potential bioavailability of
contaminants should be examined. These inlcude sediment speciation (using dilute acid extracts), acid volatile sulphides
and pore water concentrations.
Temporal variability is less relevant for sediments
which are generally deposited very slowly. When comparing test results with trigger values, and with reference site values, the median may be universally suitable as an estimate of relative concentrations.
What are particularly important are the spatial viability and particle size distribution at the sampling site, and the reference sites.
Where sediment samples within a test site clearly exceed trigger values, and background levels for the same particle size, or are judged to be hazardous, extra sampling should be undertaken to delineate contaminated zones within a site.
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Test against guideline values - Compare contaminant/strssor concentration with lower and
upper guideline values
Sediment contaminant characterisation - Measure the total and then test for dilute
acid-soluable metals, organics plus Total Organic Carbon, grain size.
Determine appropriate guideline trigger values for selected indicators( see WQG fig 3.1.1)
Define primary management aims ( see WQG fig 3.1.1)
Low Risk of Damage
or Impairment of Use
Potential Risk of Damage
or Impairment of Use
<<<< Level below lower guideline value
** Level exceeds upper guideline value >>>>
** Between Upper and
Lower Values
Potential Risk of Damage
or Impairment of Use
Check background
concentrations
NOTE: Local Biological
effects data not
required in the
decision trees
(see section 3.1.5)
<<<< Level below background level
** Level exceeds background levels >>>>
Examine factors controlling
bioavailability (optional)
eg. Acid Volatide Sulphides (AVS)
pore water concentratiuons
sediment sepciation
organic carbon
Low Risk of Damage
or Impairment of Use
Test against guideline values -
Compare bioavailable concentration
with lower guideline value
Low Risk of Damage
or Impairment of Use
Potential Risk of Damage
or Impairment of Use
<<<< Below lower guideline value
** Above lower guideline value >>>>
Conduct acute toxicity tests
<<<< ** Not toxic
Toxic >>>
Highly Contaminated
(Initiate remedial actions)
Conduct chronic toxicity tests
<<<< Not toxic
Toxic >>>
Low Risk of Damage
or Impairment of Use
Moderately Contaminated
(Initiate remedial actions)
** Further investigations are not mandatory; users may opt to
proceed to management / remedial action